Urea injection systems valves

ABSTRACT

Apparatuses and methods for urea dosing of an exhaust after treatment system are disclosed. Exemplary apparatuses include a chamber configured to receive pressurized gas at a first inlet, receive urea solution at a second inlet and provide a combined flow of pressurized gas and urea to an outlet, flow passage extending from the first inlet to a seating surface, and a valve member configured to move between an open position in which the valve member is spaced apart from the seating surface and a closed position in which the valve member contacts the seating surface. As the valve member moves from the open position to the closed position, the valve member contacts the seating surface at a first location and wipes an area of the seating surface extending from the first location in a direction toward the flow passage.

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a divisional of U.S. patent application Ser.No. 14/238,818, with a 371(c) date of Sep. 12, 2014 and with theInternational Filing Date of Aug. 22, 2012. U.S. patent application Ser.No. 14/238,818 is a U.S. National Phase application based onPCT/2012/051829, filed on Aug. 22, 2012, which claims priority to andthe benefit of U.S. Provisional Patent Application No. 61/526,102 filedAug. 22, 2011. The contents of all of these applications are herebyincorporated by reference in their entirety.

BACKGROUND

Selective catalytic reduction (“SCR”) exhaust aftertreatment systems arean important technology for reducing NOx emissions from internalcombustion engines such as diesel engines. SCR systems generally includea source of urea solution, a pump unit for pressurizing the ureasolution, a metering unit for providing a controlled amount or rate ofurea solution to an SCR catalyst, and an injector which provides ureasolution to a urea decomposition region of an exhaust flowpath locatedupstream from an SCR catalyst. Many SCR systems also utilize pressurizedgas to assist the flow of urea solution to the injector. While providingimportant reductions in NOx emissions, SCR systems suffer from a numberof shortcomings and problems. Use of urea solutions in SCR systems mayresult in growth of urea crystals or deposits on various components ofthe system which may disrupt their operation. Injector nozzles maybecome blocked due to formation of urea deposits when urea solution isexposed to elevated temperatures. Such deposits may also form on the SCRcatalyst or other components located in the exhaust flowpath orotherwise exposed to high temperatures. Leakage of urea to the ambientenvironment can damage or destroy other system components. There is along felt need for advancements mitigating these and other shortcomingsassociated with SCR systems utilizing urea solution.

SUMMARY

Certain exemplary embodiments include apparatuses including a chamberconfigured to receive pressurized gas at a first inlet, receive ureasolution at a second inlet, and provide a combined flow of pressurizedgas and urea to an outlet, a flow passage extending from the first inletto a seating surface, and a valve member configured to move between anopen position in which the valve member is spaced apart from the seatingsurface and a closed position in which the valve member contacts theseating surface. As the valve member moves from the open position to theclosed position the valve member contacts the seating surface at a firstlocation and wipes an area of the seating surface extending from thefirst location in a direction toward the flow passage. Exemplary methodsinclude closing a valve in an air supply circuit of a urea injectionsystem effective to slide a closing member across a contact surface.Further aspects, embodiments, forms, features, benefits, objects, andadvantages shall become apparent from the detailed description andfigures provided herewith.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of an exemplary air-assisted urea injectionsystem.

FIG. 2 is a sectional view of a portion of an exemplary air-assistedurea injection system.

FIG. 3 is an exploded, perspective, sectional view of certain componentsillustrated in FIG. 2.

FIGS. 4A-4D are sectional views of certain components illustrated inFIGS. 2 and 3 at different points during a valve closing event.

FIGS. 5-8 are flow diagrams of urea injection system control procedures.

FIG. 9 is a side sectional view of an exemplary pump unit of a ureainjection system.

FIG. 10 is a side sectional view of an exemplary exhaust flowpath of anSCR aftertreatment system.

FIG. 11 is a perspective view of an exemplary mixer of an SCRaftertreatment system.

FIG. 12 is a graph illustrating percent NOx conversion by several SCRaftertreatment systems with and without mixers.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

For the purposes of promoting an understanding of the principles of theinvention, reference will now be made to the embodiments illustrated inthe drawings and specific language will be used to describe the same. Itwill nevertheless be understood that no limitation of the scope of theinvention is thereby intended, any alterations and further modificationsin the illustrated embodiments, and any further applications of theprinciples of the invention as illustrated therein as would normallyoccur to one skilled in the art to which the invention relates arecontemplated herein.

With reference to FIG. 1 there is illustrated an exemplary system 100for injection of urea solution into an SCR exhaust aftertreatmentsystem. System 100 may be provided on a vehicle powered by an enginesuch as a diesel engine, or on an engine utilized in other applicationssuch power generation or pumping systems. System 100 includes a pump 134which draws urea solution from tank 140 through filter screen 138 andcheck valve 136. A preferred urea solution is diesel exhaust fluid (DEF)which comprises a solution of 32.5% high purity urea and 67.5% deionizedwater. It shall be appreciated, however, that other urea solutions mayalso be utilized. In a preferred form pump 134 is a diaphragm pump,though it shall be appreciated that other types of pumps may beutilized. Pump 134 outputs pressurized urea solution at a predeterminedpressure which flows through check valve 130, pulsation dampener 122,and filter 124 to provide pressurized urea solution to metering valve118. System 100 further includes a bypass valve 128 which is operable toopen and close to permit or prevent the flow of urea solution throughbypass line 132 to a location downstream of screen 138 where it may bereturned to the tank 140, for example, during a purging operation.

Metering valve 118 is operable to provide urea solution to blendingchamber 112 at a controllable rate. Blending chamber 112 also receives aflow of pressurized air from an air supply 102 and discharges a combinedflow of pressurized air and urea solution at outlet 116. Air supply 102may be integral to a vehicle, integral to an engine, or may be an airsupply dedicated to system 100. It shall be understood that additionalembodiments may utilize pressurized gases other than air, for example,combinations of one or more inert gases.

Air supply 102 provides pressurized air to air regulator 104. From airregulator 104 pressurized air proceeds to air shutoff valve 106 whichcan be selectably opened to allow pressurized air to flow to check valve110 and closed to obstruct the flow of pressurized air. Check valve 110opens when the air pressure at its inlet is above a threshold pressureand closes when the air pressure is below the threshold. From checkvalve 110 pressurized air flows to blending chamber 112. A combined flowof aqueous urea solution entrained in pressurized air exits blendingchamber outlet 116 and is provided to nozzle 113 which is configured toinject the combined flow into an exhaust aftertreatment system such as aurea decomposition tube or exhaust flow passage leading to an SCRcatalyst.

System 100 may be controlled and monitored by a controller 101 such asan engine control module (ECM) or a doser control module (DCM). It shallbe appreciated that the controller or control module may be provided ina variety of forms and configurations including one or more computingdevices having non-transitory memory storing computer executableinstructions, processing, and communication hardware. It shall befurther appreciated that controller may be a single device or adistributed device, and the functions of the controller may be performedby hardware or software.

Controller 101 is operatively coupled with and configured to storeinstructions in a memory which are readable and executable by controller101 to control diaphragm pump 134, air shut off valve 106, meteringvalve 118, and bypass valve 128. Controller 101 is also operativelycoupled and may receive a signal from a pressure sensor 114, pressuresensor 120 and temperature sensor 126. Pressure sensor 114 is operableto provide a signal indicating the pressure in blending chamber 112 at alocation downstream from the urea inlet and the pressurized air inlet.The pressure at this location may be pressure of a combined flow ofpressurized air and urea, pressure of air alone, pressure of urea alone,or pressure in the absence of urea and compressed air depending on theoperational state of metering valve 118 and air shut off valve 106.Temperature sensor 126 is operable to provide a signal to controller 101indicating the temperature of urea solution at a location betweendiaphragm pump 134 and metering valve 118. Pressure sensor 120 isoperable to provide a signal to controller 101 indicating the pressureof the urea solution upstream from of metering valve 118.

With reference to FIG. 2 there is illustrated an exemplary blendingdevice 200 which is operable to output a combined flow of urea solutionand pressurized air. Blending device 200 includes a metering valve 202having an outlet 203 which provides urea solution to a blending chamber204. Metering valve can be controlled by controller 101 to provide ureasolution at a controlled rate in a controlled amount. Blending chamber204 also receives a flow of pressurized air from air passage 205 whichextends from an outlet 206 to a seating surface 208. The flow ofpressurized air through air passage 205 is controlled to have a velocityand flow characteristics effective to provide an air curtain whichresists crystal formation and migration. In the illustrated form,blending chamber 204 is a substantially cylindrical passage which isconfigured so that urea received from metering valve 202 is entrained ina flow of pressurized air received from air passage 205, and a combinedflow of pressurized air and urea solution is provided to outlet member230 which is connected to an injector configured to provide the combinedflow to an exhaust aftertreatment system. Pressure sensor 207 isoperable to sense the pressure of the blended flow at a locationdownstream from urea outlet 203 and air outlet 206.

The flow of pressurized air to air passage 205 is controlled byoperation of check valve 209 and an upstream air shut off valve. Checkvalve 209 includes a closing member 210 which extends from a flexiblediaphragm 223 in a direction toward a seating surface 208. In FIG. 2closing member 210 is illustrated in a closed position in which itcontacts seating surface 208 to form a seal and prevent flow from airsupply passage 222 to air supply passage 205. Biasing member 214 appliesforge to plunger 212 which applies force to closing member 210 tomaintain check valve 209 in the closed position. Biasing member 214 isillustrated in the form of a spring but may be a variety of otherbiasing members operable to provide force to closing member 210 in adirection toward seating surface 208. Valve cover 216 contacts biasingmember 214 and holds it in position relative to plunger 212. Valve cover216 also contacts diaphragm 223 and secures it to the underlyingstructure of blending device 200.

The lower surface the diaphragm 223 is exposed to air supply passage 222which receives pressurized air from air inlet 220. The pressurized airin air supply passage 222 provides a force against the portions of thelower surface of diaphragm 223 and closing member 210 in contact withair supply passage 222. This force opposes the force applied to closingmember 210 by plunger 212 and biasing member 214. When the forceprovided by pressurized air in air supply passage 222 is greater thanthe force provided by biasing member 214 check valve 209 opens andpressurized air flows from air supply passage 222 past check valve 209to air passage 205. The opening/closing threshold pressure isestablished by the pre-loading of biasing member 214. The pre-loading ofbiasing member 214 is preferably tuned to provide rapid opening of checkvalve 209 at a pressure at or near a threshold pressure. The thresholdpressure is preferably selected to be at or near the normal operatingair pressure during urea injection, for example, 90% or more of thenormal operating air pressure. This allows check valve 209 to open onlywhen there is sufficient pressure for injection.

The threshold air pressure is also preferably selected so that checkvalve 209 opens only at or above a threshold air pressure which providesair flow characteristics effective to inhibit urea crystal growth in airsupply passage 205 and urea crystal migration toward closing member 210.The inventors have determined that for the illustrated embodiment an airflow velocity in air supply passage 205 of at least 47 m/sec. iseffective to inhibit urea crystal growth in air supply passage 205. Thethreshold air pressure may be selected to provide a margin of error onthe minimum air flow rate, for example, the pressure may be selected toprovide air flow velocity in air supply passage 205 of at least 50-55m/sec. It should be appreciated, however, that the threshold airpressure should not exceed a magnitude where it would provides undesiredair flow characteristics.

It shall be appreciated that the magnitude the threshold air pressureand associated air flow velocity effective to inhibit urea crystalgrowth may vary depending upon the characteristics of air supply passage205, check valve 209 and blending chamber 204. In the illustratedembodiment air passage 205 extends over a length of about 6 mm and has asubstantially constant diameter of about 1 mm. For this configuration apressure of 3.45 bar gauge +/−0.4 bar gauge or greater has beendetermined to provide desired air flow characteristics effective toinhibit urea crystal growth. Additional embodiments include air supplypassages with different characteristics and have different threshold airpressure values and associated air flow velocities effective to inhibiturea crystal growth.

With reference to FIG. 3 there is illustrated an exploded sectional viewof certain components illustrated in FIG. 2. Flexible diaphragm 223includes a fold 225 that accommodates flexing to move closing member 210and provides an alignment feature for plunger 212. Flexible diaphragmfurther includes a peripheral ridge 224 which is contacted by housing toretain diaphragm 223 in position and provides an alignment feature forthe housing 216 relative to the diaphragm 223. A retaining clip 226engages a groove 227 on plunger 214 to retain plunger and biasing memberin place relative to housing 216. FIG. 3 illustrates closing member 210in the form of a ball shaped or spheroid protrusion from diaphragm 223.It shall be understood that additional embodiments include closingmembers in various other configurations, forms and shapes.

With reference to FIGS. 4A-4D there are illustrated detailed views ofclosing member 210 in various positions relative to seating surface 208which illustrate the movement and deformation of closing member 210during closing of valve 209. FIG. 4A illustrates closing member 210 inan open position relative to seating surface 208. In the open positionpressurized air is permitted to flow from air supply passage 222 betweenvalve closing member 210 and seating surface 208 and to air passage 205.FIG. 4B illustrates valve closing member 210 at the point during a valveclosing event where valve closing member 210 first contacts seatingsurface 208 at location 228. FIG. 4C illustrates valve closing member210 at a later point in the valve closing event. At this point valveclosing member 210 has traveled across seating surface 208 effective towipe an area 229 of seating surface 208. During valve closing theclosing member 210 slides across seating surface 208 and alsoelastomerically deforms to conform to the shape of seating surface 208.FIG. 4D illustrates valve closing member 210 in a fully closed position.Valve closing member 210 has slid across and wiped additional area 230of seating surface 208.

The interaction of closing member 210 with seating surface 208 providesa self-cleaning capability for check valve 209. The sliding and wipingmotion of closing member 210 across seating surface 208 is preferablyeffective to dislodge and wipe away urea crystals from seating surface208. The portion of closing member 210 that contacts seating surface 208preferably has a hardness of 50-70 Shore A to allow sufficientelastomeric deformation but provide sufficient hardness to dislodge andwipe urea crystals from surface 208. It shall be appreciated that otherembodiments include closing members with different material propertiesthat achieve a sliding and wiping of a seating surface with sufficientforce to dislodge and wipe urea crystals from the seating surface.

With reference to FIG. 5 there is illustrated a flow diagram of a washcycle procedure 240 for a of a urea injection system. Procedure 240begins at operation 241 in which a control routine for a urea injectionsystem for an SCR exhaust aftertreatment system is initiated. Fromoperation 241, procedure 240 proceeds to operation 242 which interpretsan engine key-on event. The operation to interpret an engine key-onevent may include, additionally or alternatively, interpreting acommunication or other parameter indicating that operations of the fluidinjector are going to resume after a shutdown, or after a period ofinactivity of a specified length that may not include a completeshutdown. If an engine system key-on event is interpreted to be true,procedure 240 proceeds to operation 243. If an engine system key-onevent is interpreted to be false, operation 241 repeats.

Operation 243 interprets a urea delivery request. The operation tointerpret the urea delivery request includes a determination that ureainjection for exhaust aftertreatment has been commanded or requested orthat actual usage of the fluid injector is imminent. In certainembodiments, a command for the fluid injector to inject urea serves asthe urea delivery request. If a urea delivery request is determined tobe greater than zero, procedure 240 proceeds to operation 244. If a ureadelivery request is not determined to be greater than zero, operation243 repeats.

Operation 244 commands an air shut off valve to close. The shut offvalve may be, for example, valve 106 which is illustrated and describedabove in connection with FIG. 1. From operation 244 procedure 240proceeds to timer evaluation 245. Timer evaluation 245 is configured toevaluate whether a first predetermined time has elapsed. The firstpredetermined time is selected to ensure that an air flow passage hasbeen sealed to prevent urea solution from flowing past the seal. Incertain embodiments timer 245 is configured to account for the timerequired for a check valve positioned downstream from an air shut offvalve to close such as is described above in connection with FIGS. 1-4.If timer evaluation 245 determines that the first predetermined time hasnot elapsed procedure 240 proceeds to operation 246 which increments thetimer and returns to timer evaluation 245

If timer evaluation 245 determines that the first predetermined time haselapsed procedure 240 proceeds to operation 247 which provides ureasolution to a portion of the system to be washed. In certain embodimentsurea is provided to a blending chamber such as blending chamber 204illustrated and described above in connection with FIG. 2. In certainembodiments urea is provided at a rate effective to fill at least aportion of the blending chamber to dissolve or detach urea crystalswhich may have formed therein. In certain embodiments urea is providedat a rate effective to fill at least a portion of an air supply passagein flow communication with the blending chamber, such as air supplypassage 205 illustrated and described above in connection with FIG. 2,to dissolve or urea crystals which may have formed therein. In certainembodiments urea solution is provided to substantially fill the blendingchamber and the air supply passage.

From operation 247 procedure 240 proceeds to timer evaluation 248 whichevaluates whether a second predetermined time period has elapsed. Thesecond predetermined time is preferably a time that allows the ureacrystals to dissolved or detach from the portion of the system providedwith urea solution. The second predetermined time may be determinedempirically through data sampling with a test fluid injector. In certainembodiments, the predetermined time may be a function of the urea flowrate during cleaning, the temperature of the supplied urea, atemperature of the fluid injector (e.g. from an ambient temperature orother estimate), and/or a function of the flow velocity or Reynoldsnumber of the urea flowing within the fluid injector having a mixingpassage of the given cross-section.

If timer evaluation 248 determines that the second predetermined timehas not elapsed, procedure 240 proceeds to operation 249 whichincrements the timer and returns to operation 247. If timer evaluation248 determines that the second predetermined time has elapsed, procedure240 proceeds to operation 250 which ends the wash cycle. In someembodiments procedure 240 may be repeated only once during a key oncycle. In other embodiments procedure 240 may repeat periodically orafter a predetermined time has lapsed. In further embodiments procedure240 may repeat when a system obstruction condition is detected.

Certain operations described herein include operations to interpret oneor more parameters. Interpreting, as utilized herein, includes receivingvalues by any method known in the art, including at least receivingvalues from a datalink or network communication, receiving an electronicsignal (e.g. a voltage, frequency, current, or PWM signal) indicative ofthe value, receiving a software parameter indicative of the value,reading the value from a memory location on a computer readable medium,receiving the value as a run-time parameter by any means known in theart, and/or by receiving a value by which the interpreted parameter canbe calculated, and/or by referencing a default value that is interpretedto be the parameter value.

With reference to FIG. 6 there is illustrated a flow diagram accordingto a further exemplary wash cycle procedure 260 for a urea injectionsystem. Procedure 260 begins at conditional 261 which evaluates one ormore initialization conditions. In certain embodiments theinitialization conditions include evaluating whether a key-on value istrue, a urea supply request is true, and a urea pump primed pressurecheck is true. If conditional 261 determines that the initializationconditions are not true, it repeats the evaluation of the one or moreinitialization conditions. If conditional 261 determines that theinitialization conditions are true, it proceeds to operation 262.

Operation 262 commands an air shut off valve to close. The air shut offvalve may be, for example, air shutoff valve 106 illustrated anddescribed above in connection with FIG. 1. From operation 262 procedure260 proceeds to conditional 263. Conditional 263 evaluates whetherpressure information P1 is less than a threshold pressure THP1. In anexemplary embodiment, pressure information P1 is provided by pressuresensor 207 which is illustrated and described above in connection withFIG. 2. In other embodiments pressure information P1 is provided by oneor more pressure sensors positioned in other locations downstream froman air inlet and a urea inlet to a blending chamber. Threshold THP1 is athreshold pressure identifying that a valve has closed to prevent theflow of pressurized air through a an air supply passage leading to theblending chamber. In an exemplary embodiment, threshold THP1 is selectedto indicate that check valve 209 has closed based upon an expectedpressure value such as atmospheric pressure or a value greater thanatmospheric pressure accounting for pressure seen at the outlet of theinjection system such as 130 kPa. If conditional 263 is false it repeatsthe evaluation. If conditional 263 is true it proceeds to operation 264.

Operation 264 performs a wash injection of urea solution into a blendingchamber with an air shut off valve closed. In certain embodiments ureais provided to a blending chamber such as blending chamber 204illustrated and described above in connection with FIG. 2. In certainembodiments urea is provided at a rate effective to fill at least aportion of the blending chamber to dissolve or detach urea crystalswhich may have formed therein. In certain embodiments urea is providedat a rate effective to fill at least a portion of an air supply passagein flow communication with the blending chamber, such as air supplypassage 205 illustrated and described above in connection with FIG. 2,to dissolve or urea crystals which may have formed therein. In certainembodiments urea solution is provided to substantially fill the blendingchamber and the air supply passage.

From operation 264 procedure 260 proceeds to conditional 265.Conditional 265 is a timer which tests whether an elapsed time t1 isgreater than a time threshold THt1. The time threshold THt1 is selectedto allow the urea crystals to dissolved or detach from the portion ofthe system provided with urea solution. The time threshold THt1 may bedetermined empirically through data sampling with a test fluid injector.In certain embodiments, the time threshold THt1 may be a function of theurea flow rate during cleaning, the temperature of the supplied urea, atemperature of the fluid injector (e.g. from an ambient temperature orother estimate), and/or a function of the flow velocity or Reynoldsnumber of the urea flowing within the fluid injector having a mixingpassage of the given cross-section. If conditional 265 is false, itrepeats. If conditional 265 is true, it proceeds to operation 266.

Operation 266 opens the air shutoff valve and returns control of ureadosing to a control routine that provides urea solution at a rate neededfor the SCR catalyst to reduce NOx generated by the engine which may bereferred to as normal urea dosing operation. From operation 266,procedure 260 proceeds to conditional 267. In certain embodimentsconditional 267 tests whether pressure P2 is less than a pressurethreshold THP2. In certain embodiments, pressure P2 is the pressuresensed by pressure sensor 207 which is illustrated and described abovein connection with FIG. 2, and pressure threshold THP2 is a thresholdwhich indicates a blockage upstream from pressure sensor 207 such as canoccur through the accumulation or growth of urea crystals in blendingchamber 204. In certain embodiments conditional 267 also implements atimer which tests whether a time t2 is greater than a time thresholdTHt2 which indicates a minimum delay between sequential wash cycles. Incertain embodiments conditional 267 evaluates whether either pressure P2is less than pressure threshold THP2 or whether time t2 is greater thantime threshold THt2. In certain embodiments conditional 267 evaluateswhether both pressure P2 is less than pressure threshold THP2 and timet2 is greater than time threshold THt2. If conditional 267 is false, itrepeats. If conditional 267 is true, it proceeds to operation 262.

With reference to FIGS. 7A and 7B there is illustrated a flow diagramaccording to an exemplary wash cycle process 270 for a urea injectionsystem which may be, for example, a system as illustrated and describedin connection with FIGS. 1-4 or another system. Process 270 begins anconditional 271 which evaluates whether initialization conditions aretrue. In the illustrated embodiment the initialization conditionevaluation includes evaluating whether a key on condition is trueindicating that an operator has turned a vehicle key on, and evaluatingwhether a urea pump prime complete condition is true indicating that aurea solution pump has successfully primed to provide urea solutionpressure above an operation threshold, for example, urea solutionpressure above 420 kPa. If the initialization conditions are not trueconditional 271 repeats. If the initialization conditions are trueprocess 270 proceeds to conditional 272.

Conditional 272 evaluates whether an SCR system is ready. A number ofcriteria may be utilized to evaluate whether the SCR system is ready. Incertain embodiments conditional 272 evaluates whether an SCR catalystinlet temperature is within a predetermined temperature range, forexample between 200° C. and 600° C., evaluates whether an SCR catalystbed temperature is within a predetermined range, for example between180° C. and 600° C., and evaluates whether an exhaust mass flow is abovea predetermined value, for example, above 30 grams per second. Theseevaluations are effective to evaluate temperature and exhaust flowconditions associated with an injector nozzle that provides ureasolution to an exhaust flowpath of the SCR system are in a rangeacceptable to avoid nozzle blockage due to insufficient temperature,excessive temperature, or insufficient exhaust flow. Additionalembodiments utilize other criteria for determining whether the SCRsystem is ready including, for example, alternate temperature ranges,alternate flow rates, temperature measurements at alternate locationssuch as at or near the injector nozzle or a conduit in which theinjector nozzle is disposed, exhaust temperature measurements,measurements by virtual sensors instead of or in addition physicalsensors, as well as other criteria relating to SCR catalyst conditions,engine operation, and exhaust output of the engine. Certain embodimentsevaluate whether the SCR system is ready based upon a receipt of a ureadosing command which is generated only when a separate routine hasdetermined that the SCR system is ready and dosing can occur.

If conditional 272 determines that the SCR system is not ready, itrepeats. If conditional 272 determines that the SCR system is ready,process 270 proceeds to operation 273 which performs a wash cycle whichis illustrated and described in connection with FIG. 8. Operation 273may also perform other wash cycle operations such as those described inconnection with FIGS. 5 and 6. From operation 273 process 270 proceedsto operation 274 which starts a smart wash timer and initiates operationof a urea dosing system to provide urea solution at a rate needed forthe SCR catalyst to reduce NOx generated by the engine which may bereferred to as normal urea dosing operation.

From operation 274 process 270 proceeds to conditional 275 whichevaluates whether the pressure of a combined flow of pressurized gas andurea is below a wash cycle threshold for a predetermined time, forexample, less than 310 kPa for 10 seconds. If conditional 275 determinesthat the pressure of the combined flow is not less than the wash cyclethreshold, it repeats. If conditional 275 determines that the pressureof the combined flow is below the wash cycle threshold for thepredetermined time, process 270 proceeds to conditional 276.Alternatively, in certain embodiments, if conditional 275 determinesthat the pressure of the combined flow is below the wash cycle thresholdfor the predetermined time, process 270 evaluates whether temperature ofan SCR catalyst is below a threshold, for example, 400° C. If thetemperature is at or below the threshold, process 270 proceeds toconditional 276. If the temperature is above the threshold, process 270proceeds to conditional 281.

Conditional 276 evaluates whether the smart timer has reached apredetermined time limit. The predetermined time is selected to ensuresthat a wash cycle is not performed too frequently so as to negativelyimpact NOx conversion efficiency to an undesired or unacceptable degreeor crate an undesirable or unacceptable increase the risk of injectionnozzle blockage by urea deposits. If conditional 276 determines that thetime limit has not been reached, it repeats. If conditional 276determines that the time limit has been reached, process 270 proceeds toconditional 281.

Conditional 281 evaluates whether a pressure of the combined flow ofcompressed gas and urea is less than an on-board diagnostic (OBD)threshold for predetermined time, for example, below 300 kPa for 10seconds. If conditional 281 determines that the pressure of the combinedflow is not below the diagnostic threshold for the predetermined time,process 270 returns to conditional 275. If conditional 281 determinesthat the pressure of the combined flow is above the diagnostic thresholdfor the predetermined time, process 270 proceeds to conditional 282.

Conditional 282 evaluates whether the SCR system is ready, for example,using the criteria described above in connection with conditional 272,or other criteria indicating performance or operation of an SCRcatalyst. If conditional 282 determines that the SCR system is not readyfor operation, process 270 returns to conditional 275. If procedure 282determines that the SCR system is ready for operation, process 270proceeds to operation 283 which sets a low pressure fault code which mayindicate any of several failure modes including, insufficient pressurein an air supply tank due to a leak or a compressor malfunction, airshut-off valve malfunction preventing the valve from opening, air supplyline blockage or leaks, urea crystallization obstruction or air flow, orother leaks, blockages or component failures associates with the airsupply system. Certain embodiments may omit conditional 282 and proceedfrom conditional 281 to operation 283.

If conditional 276 determines that the smart wash timer has reached thepredetermined time threshold, process 270 proceeds to operation 277which evaluates whether the SCR system is ready for operation, forexample, as described in connection with conditional 272, or byevaluating whether criteria indicating that the SCR aftertreatmentsystem is ready for operation. If conditional 277 determines that theSCR system is not ready, it repeats. If conditional 277 determines thatthe SCR system is ready for operation, process 270 proceeds to operation278.

Operation 278 performs a wash cycle which is illustrated and describedin connection with FIG. 8. Operation 273 may also perform other washcycle operations such as those described in connection with FIGS. 5 and6. From operation 278 process 270 proceeds to operation 279. Operation279 resumes normal dosing operation of the urea injection system. Fromoperation 279 process 270 proceeds to conditional 280 which evaluateswhether a pressure of the combined flow of urea solution and compressedgas is below a wash cycle threshold for a predetermined time, forexample, less than 300 kPa for 20 seconds, less than 310 kPa for 20seconds, or another predetermined time or pressure value. If conditional280 determines that the pressure of the combined flow is not below thepredetermined pressure for the predetermined time, process 270 proceedsto operation 274 if conditional 280 determines that the pressure of thecombined flow is below the predetermined pressure for the predeterminedtime, process 270 proceeds to conditional 276.

With reference to FIG. 8, there is illustrated a flow diagram accordingto an exemplary wash cycle 273. Wash cycle 273 begins with operation 291which closes an air shutoff valve and interrupts normal dosing operationto stop supplying urea solution. From operation 291 wash cycle 273proceeds to conditional 292. Conditional 292 evaluates whether anaverage pressure of a flow compressed gas is less than the predeterminedpressure, for example 130 kPa or another predetermined pressure, andwhether a timer is less than a predetermined time, for example less than6 seconds or another predetermined time. If conditional 292 determinesthat the pressure of the combined flow is below the predeterminedthreshold and the timer is below the time threshold, wash cycle 273proceeds to operation 292 which provides urea solution to a dosingsystem component such as a blending chamber at a predetermined rate fora predetermined time, for example, 0.8 ml per second for 3 seconds, 0.6ml per second for 4 seconds, or another rate for another time effectiveto dissolve or detach urea crystals from the blending chamber or otherportions of a urea solution injection system.

If conditional 292 determines that the pressure of the combined flow isnot below the predetermined pressure or the timer is not less than thepredetermined time, or both, wash cycle 278 proceeds to operation 294which sets a fault code indicating a blocked injection nozzle. Incertain embodiments, if conditional 292 determines that the pressure ofthe combined flow is not below the predetermined pressure or the timeris not less than the predetermined time, or both, wash cycle 273 waits apredetermined time, for example, 6 seconds, and proceeds to aconditional which evaluates whether an average pressure of a flowcompressed gas is less than a second predetermined pressure thresholdwhich may be the same as or different from the predetermined pressure ofconditional 292, for example 130 kPa, 150 kPa, or another predeterminedpressure. If it is determined that the pressure is at or below thesecond threshold, wash cycle 273 proceeds to operation 292. If it isdetermined that the pressure is above the second threshold wash cycle278 proceeds to operation 294.

In certain embodiments operation 292 provides urea to a blending chambersuch as blending chamber 204 illustrated and described above inconnection with FIG. 2. In certain embodiments urea is provided at arate effective to fill at least a portion of the blending chamber todissolve or detach urea crystals which may have formed therein. Incertain embodiments urea is provided at a rate effective to fill atleast a portion of an air supply passage in flow communication with theblending chamber, such as air supply passage 205 illustrated anddescribed above in connection with FIG. 2, to dissolve or urea crystalswhich may have formed therein. In certain embodiments urea solution isprovided to substantially fill the blending chamber and the air supplypassage.

In certain embodiments wash cycle 273 may also perform a metering valveblockage diagnostic during operation 292. During operation 292 ureapressure upstream from a urea metering valve is monitored. If apredetermined pressure drop is not observed, a fault code is set toindicate a metering valve blockage. Otherwise wash cycle 273 proceeds asdescribed above. The metering valve blockage diagnostic may be performedduring each wash cycle or only during the first wash cycle initiatedafter a key on event.

With reference to FIG. 9, there is illustrated an exemplary pump 300 foran exhaust aftertreatment urea injection system. Pump 300 includes apump body 302, a pump bonnet 304 and a pump head 306 which are coupledwith threaded fasteners 308. A flexible diaphragm is clamped betweenpump bonnet 304 and pump body 302 at a peripheral region of thediaphragm 310. A surface of diaphragm 310 faces and defines a boundaryof a compression chamber 314. A seal is formed in the peripheral regionwhere diaphragm 310 is clamped between pump bonnet 304 and pump body302. A diaphragm bead 316 positioned at the peripheral region ofdiaphragm 310 contributes to the formation of the seal. An annularcollection chamber 318 surrounds the seal formed where pump bonnet 304and pump body 302 clamp diaphragm 310. The collection chamber 318 issealed from the ambient environment by an sealing member 320 which inthe illustrated embodiment is an O-ring positioned between and clampedby pump bonnet 304 and pump body 302 surrounding collection chamber 318.An actuator 312 is coupled with diaphragm 310 and is operable to movediaphragm 310 to vary the volume of compression chamber 314.

During operation of pump 300 the actuator 312 drives the diaphragm 310to alternately expand and contract the volume of compression chamber314. This operation creates a suction force at the pump inlet whichdraws urea solution from a urea supply source in the directionsindicated by arrows 331, 332 and 334 through inlet flow path 330. Ureasolution is drawn through a check valve 333 which allows flow from flowpath 330 to chamber 314 but prevents flow in the opposite direction.While not illustrated, it should be understood that pump 300 alsoincludes an outlet flow path in flow communication with chamber 314 anda second check valve that permits flow of pressurized urea solution fromchamber 314 to the outlet flow path but not in the opposite direction.During operation of pump 300 pressurized urea solution is provided tothe pump outlet.

During compression stroke actuator 312 moves diaphragm 310 to reduce thevolume of chamber 314. During the compression stroke the pressure ofurea solution within chamber 314 may be sufficiently great so as tocause leakage through the seal formed by pump bonnet 304 and pump body302 clamping diaphragm 310. Solution that leaks past the seal iscaptured by collection chamber 316. Suction generated by the operationof pump 300 draws urea solution that is leaked into collection chamber318 through return passage 322 and into inlet passage 330 where itreturns to the inlet of chamber 314. During operation of pump 300,chamber 314 and return passage 322 are under substantially continuoussuction. Thus, even if the seal formed by sealing member 320 iscompromised, suction provided by operation of the pump 300 will draw airfrom the ambient environment to the pump inlet and will prevent ureasolution from leaking to the ambient environment.

With reference to FIG. 10 there is illustrated an exemplary exhaust flowpath 700 for an SCR aftertreatment system. Exhaust flow path 700includes an exhaust source 702 which may be a diesel engine for example.Exhaust source 702 provides a flow of exhaust through conduit 730. Amixer 720 is disposed in the conduit 730. An injection nozzle 710 isdisposed in location downstream from the mixer 720 at or about thecenterline of conduit 730. The injection nozzle 710 injects urea in thedirection of exhaust flow as indicated by spray 712 and the associatedarrow. Spray 712 is distributed generally uniformly in the centralregion of flow path 730 but not distributed uniformly in the peripheralregion of flow path 730. Mixer 720 imparts a swirl in exhaust flowingthrough the peripheral region of conduit 730 while allowing flow tocontinue to proceed normally through the central portion of conduit 730.In this manner exhaust back pressure is minimized by providing minimalinstruction to obtain exhaust swirl only in the location where it isneeded. The spray of urea solution 712 introduced into conduit 730decomposes along the length of conduit 730 downstream from injectionnozzle 710 to form ammonia. Ammonia is provided from outlet 742 to SCRcatalyst 750 of catalyst unit 740 which functions to reduce emissions ofNOx in the exhaust.

With reference to FIG. 11 there is illustrated a detailed perspectiveview of mixer 720. Mixer 720 includes a base portion 729 which can beattached to the interior surface of conduit 730 and a plurality of bentvanes 720-728. The central region of the mixer is open to allow flow toproceed through the mixer without encountering vanes that impart swirl.Mixer 720 can be formed from a stock sheet of metal which is cut, bentand rolled to the proper diameter to provide scalability for multipleexhaust conduit diameters. Swirl provided by mixer 740 is also scalablefor a given exhaust conduit diameter by varying the number of swirlvanes and their geometries thereby reducing or increasing the deltapressure associated with the addition of mixer 740, depending on the NOxreduction desired.

With reference to FIG. 12 there is illustrated a graph of percent NOxconversion at different engine operating conditions for two differenturea dosers with and without a mixer, as well as a conventional systembaseline. The data of FIG. 12 illustrates that incremental improvementsin NOx conversion are observed at each operational point with theinclusion of the mixer. It is further seen from the data in FIG. 12 thatgreater improvements are observed at high space velocity values for theaftertreatment system utilized in the test.

Certain exemplary embodiments will now be further described. Certainexemplary embodiments comprise apparatuses for urea dosing of an exhaustaftertreatment system. Certain exemplary apparatuses comprise a chamberconfigured to receive pressurized gas at a first inlet, receive ureasolution at a second inlet, and provide a combined flow of pressurizedgas and urea solution to an outlet, a flow passage extending from thefirst inlet to a seating surface, and a valve member configured to movebetween an open position in which the valve member is spaced apart fromthe seating surface and a closed position in which the valve membercontacts the seating surface. As the valve member moves from the openposition to the closed position the valve member contacts the seatingsurface at a first location and wipes an area of the seating surfaceextending from the first location in a direction toward the flowpassage. In certain forms the valve member deforms as it wipes the areaof the seating surface. In certain forms the valve member comprises aball-shaped portion in the open position which contacts the seatingsurface and deforms as it moves to the closed position. In certain formsthe valve member comprises a first surface that receives force from abiasing member, a second surface that receives force from pressurizedgas. In certain forms the valve member is biased toward the closedposition by the force from the biasing member and moves to the openposition when the pressurized gas has a pressure above a pressurethreshold. In certain forms the seating surface comprises afrustoconical surface. In certain forms a spheroid protrusion of thevalve member contacts the frustoconical portion and deforms duringmovement from the open position to the closed position to wipe the area.In certain forms the valve member dislodges urea crystals formed on theseating surface as it wipes the seating surface. In certain forms thevalve member comprises a flexible diaphragm having a ball-shapedprotrusion extending in a direction toward the seating surface, the ballshaped protrusion being space apart from the seating surface in the openposition, contacting the seating surface in the closed position, andwiping the area of the seating surface as it moves from the openposition to the closed position. Certain forms further comprise ametering valve configured to provide urea solution to the second inletand an air shut-off valve configured to selectably shut off a supply ofpressurized gas to the valve member.

Certain exemplary embodiments are methods comprising providing a ureadosing system including a gas flow path in fluid communication with ablending chamber, a source of urea solution in fluid communication withthe blending chamber, and a valve in fluid communication with the gasflow path, the valve including a closing member moveable relative to acontact surface, maintaining the closing member in a first positionwherein the closing member is spaced apart from the contact surface,moving the closing member to a second position wherein the closingmember contacts the contact surface, and moving the closing member to athird position wherein the closing member contacts a greater area of thecontact surface than in the second position. The closing member slidesalong the contact surface during movement from the second position tothe third position. In certain forms the closing member deforms duringmovement from the second position to the third position. In certainforms the maintaining the closing member in the first position includesproviding gas pressure to the valve above a pressure threshold. Incertain forms the moving the closing member to the second positionincludes providing gas pressure to the valve below the pressurethreshold. In certain forms the closing member wipes urea crystals fromthe contact surface during movement from the second position to thethird position. In certain forms the closing member comprises a ballshaped portion and the closing surface is funnel shaped.

Certain exemplary embodiments comprise urea dosing systems for exhaustaftertreatment. Certain exemplary systems comprise a source ofpressurized gas, a check valve in fluid communication with the source ofpressurized gas, the check valve including a closing member and aseating surface, the closing member being moveable relative to theseating surface to open and close the check valve, a flow passage influid communication with the check valve, a blending chamber in fluidcommunication with the flow passage, and a metering valve in fluidcommunication with the blending chamber, the metering valve configuredto supply urea solution to the blending chamber. The closing memberapplies a wiping force to the contact surface as the check valve closes.In certain forms the wiping force is applied over an area of the contactsurface in a direction toward the flow passage. In certain forms theclosing member comprises a spheroid portion that applies the wipingforce to the contact surface. In certain forms the contact surface isfrustoconical and the spheroid potion deforms as it applies the wipingforce to the contact surface. In certain forms the wiping force iseffective to remove urea crystals from the contact surface as the checkvalve closes. In certain forms the closing member elastomericallydeforms as it applies the wiping force. In certain forms the wipingforce is applied over an area of the seating surface extending from afirst location of the seating surface to a second location of theseating surface, the first location being upstream from the secondlocation relative to a flow direction of pressurized gas from the sourceto the flow passage. In certain forms the flow passage providespressurized gas to the bending chamber in a direction substantiallyperpendicular to the flow of urea solution from the metering valvethrough the blending chamber.

While the invention has been illustrated and described in detail in thedrawings and foregoing description, the same is to be considered asillustrative and not restrictive in character, it being understood thatonly certain exemplary embodiments have been shown and described andthat all changes and modifications that come within the spirit of theinventions are desired to be protected. It should be understood thatwhile the use of words such as preferable, preferably, preferred or morepreferred utilized in the description above indicate that the feature sodescribed may be more desirable, it nonetheless may not be necessary andembodiments lacking the same may be contemplated as within the scope ofthe invention, the scope being defined by the claims that follow. Inreading the claims, it is intended that when words such as “a,” “an,”“at least one,” or “at least one portion” are used there is no intentionto limit the claim to only one item unless specifically stated to thecontrary in the claim. When the language “at least a portion” and/or “aportion” is used the item can include a portion and/or the entire itemunless specifically stated to the contrary.

What is claimed is:
 1. An method comprising: providing a urea dosingsystem including a gas flow path in fluid communication with a blendingchamber, a source of urea solution in fluid communication with theblending chamber, and a valve in fluid communication with the gas flowpath, the valve including a closing member moveable relative to acontact surface; maintaining the closing member in a first positionwherein the closing member is spaced apart from the contact surface;moving the closing member to a second position wherein the closingmember contacts the contact surface; and moving the closing member to athird position wherein the closing member contacts a greater area of thecontact surface than in the second position; wherein the closing memberslides along the contact surface during movement from the secondposition to the third position.
 2. A method according to claim 1 whereinthe closing member deforms during movement from the second position tothe third position.
 3. A method according to claim 1 wherein themaintaining the closing member in the first position includes providinggas pressure to the valve above a pressure threshold.
 4. A methodaccording to claim 3 wherein the moving the closing member to the secondposition includes providing gas pressure to the valve below the pressurethreshold.
 5. A method according to claim 1 wherein the closing memberwipes urea crystals from the contact surface during movement from thesecond position to the third position.
 6. A method according to claim 1wherein the closing member comprises a ball shaped portion and theclosing surface is funnel shaped.
 7. A urea dosing system for exhaustaftertreatment, the system comprising: a source of pressurized gas; acheck valve in fluid communication with the source of pressurized gas,the check valve including a closing member and a seating surface, theclosing member being moveable relative to the seating surface to openand close the check valve; a flow passage in fluid communication withthe check valve; a blending chamber in fluid communication with the flowpassage; and a metering valve in fluid communication with the blendingchamber, the metering valve configured to supply urea solution to theblending chamber; wherein the closing member applies a wiping force tothe contact surface as the check valve closes.
 8. A system according toclaim 7 wherein the wiping force is applied over an area of the contactsurface in a direction toward the flow passage.
 9. A system according toclaim 7 wherein the closing member comprises a spheroid portion thatapplies the wiping force to the contact surface.
 10. A system accordingto claim 9 wherein the contact surface is frustoconical and the spheroidpotion deforms as it applies the wiping force to the contact surface.11. A system according to claim 7 wherein the wiping force is effectiveto remove urea crystals from the contact surface as the check valvecloses.
 12. A system according to claim 7 wherein the closing memberelastomerically deforms as it applies the wiping force.
 13. A systemaccording to claim 7 wherein the wiping force is applied over an area ofthe seating surface extending from a first location of the seatingsurface to a second location of the seating surface, the first locationbeing upstream from the second location relative to a flow direction ofpressurized gas from the source to the flow passage.
 14. A systemaccording to claim 7 wherein the flow passage provides pressurized gasto the bending chamber in a direction substantially perpendicular to theflow of urea solution from the metering valve through the blendingchamber.